Neville T. Moxon, Jonathan H. Moffett, Anthony K. Gregson
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引用次数: 6
Abstract
A series of compounds with the empirical formulae Fe(hfa)2OR (Hfha = 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione, R = CH3, C2H5, sec-C4H9) and the parent material Fe(hfa)3 have been prepared and characterized using analytical data, IR and optical spectroscopy, magnetic susceptibility measurements and powder X-ray diffraction. The Fe(hfa)2OR adducts are antiferromagnetic dimers with J ∼ 12 cm−1. Unusual products have been isolated when ethylene glycol is used as the alcohol.
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