Effect of ZSM-5 Acidity in Enhancement of Methanol-to-Olefins Process

H. Hambali, A. A. Jalil, T. J. Siang, A. Abdulrasheed, N. Fatah, I. Hussain, M. Azami
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引用次数: 6

Abstract

The skyrocketing demand for olefins especially propylene, have necessitated continuous efforts in finding alternate route for olefins production. Hence, methanol to olefins (MTO) was recognized as a feasible process since methanol could simply be mass produced from any gasifiable carbon-based feedstock, such as natural gas, coal, and biomass. Essentially, obtaining a more stable catalyst would improve economy of the MTO process. Acidity of catalyst has major influence in MTO, thus it is an indispensable parameter for conversion of methanol into value-added products. The present paper discusses the reactions involved in MTO process and the effect of acidity in enhancement of light olefin selectivity and catalytic stability. The paper also captured perspectives of crucial research and future direction for catalysts development and technologies that can potentiallly boost olefin production and make it competitive with the conventional olefin production processes.
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ZSM-5酸度对甲醇制烯烃过程强化的影响
对烯烃尤其是丙烯的需求急剧上升,需要不断努力寻找烯烃生产的替代途径。因此,甲醇制烯烃(MTO)被认为是一种可行的工艺,因为甲醇可以简单地从任何可气化的碳基原料(如天然气、煤和生物质)中大量生产。从本质上讲,获得更稳定的催化剂将提高MTO工艺的经济性。催化剂的酸度对MTO有重要影响,是甲醇转化为高附加值产品不可缺少的参数。本文讨论了MTO过程中所涉及的反应,以及酸度对提高轻烯烃选择性和催化稳定性的作用。该论文还阐述了催化剂开发和技术的关键研究和未来发展方向,这些技术可能会提高烯烃产量,并使其与传统的烯烃生产工艺竞争。
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