{"title":"Zero-Field Splitting and g-Values of d8 Ions in a Trigonal Crystal Field","authors":"A. K. Petrosyan, A. Mirzakhanyan","doi":"10.1002/PSSB.2221330136","DOIUrl":null,"url":null,"abstract":"On the basis of the crystal-field theory the zero-field splitting and g-values of the 3A2 ground state for d8 impurity ions in a trigonally distorted octahedral field are calculated. Using perturbation theory the analytical expressions connecting the spin-Hamiltonian parameters with the crystal-field parameters are obtained. It is shown that experimental data for Cu3+ in Al2O3, and Ni2+ in Al2O3, α-LiIO3, LiNbO3 can be explained taking into account the influence of all the excited levels on the ground state. \n \n \n \n[Russian Text Ignored].","PeriodicalId":11087,"journal":{"name":"Day 1 Tue, January 11, 2022","volume":"206 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1986-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"42","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Day 1 Tue, January 11, 2022","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/PSSB.2221330136","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 42
Abstract
On the basis of the crystal-field theory the zero-field splitting and g-values of the 3A2 ground state for d8 impurity ions in a trigonally distorted octahedral field are calculated. Using perturbation theory the analytical expressions connecting the spin-Hamiltonian parameters with the crystal-field parameters are obtained. It is shown that experimental data for Cu3+ in Al2O3, and Ni2+ in Al2O3, α-LiIO3, LiNbO3 can be explained taking into account the influence of all the excited levels on the ground state.
[Russian Text Ignored].
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