Influence of Fe3+ Ion Substitution on Thermal and Dielectric Properties of Titanium Dioxide

Shirajahammad M. Hunagund, P. Chavan, Vani R. Desai, L. R. Naik, J. Kadadevarmath, Ashok H. Sidarai
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引用次数: 1

Abstract

Thermal and dielectric characteristics of Fe2O3 doped TiO2 (FDT) nanopowder is investigated. Formation of FDT was prepared using the formula [1-x] TiO2 + [x] Fe2O3 by solid state reaction method. The Surface morphology was studied using atomic force microscopy (AFM) technique; it reveals the average particle size in the range of 180 to 200nm. FT-IR analysis reveals weak transmittance bands between 1020 to 1650 cm-1 and 2800 to 3500 cm-1 which shows a gradual decrease in peak intensities with an increase of Fe concentration. Thermal stability was assessed by Thermogravimetric analysis (TGA). Results of TGA Profiles indicate that all FDT nanopowder was found to be thermally stable between 400 °C to 600 °C. The dielectric behavior of the said composite has been investigated as a function of frequency (20 Hz - 1 MHz) at room temperature and it is observed that the dielectric constant decreases with increasing frequency indicating dispersion behavior.
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Fe3+离子取代对二氧化钛热性能和介电性能的影响
研究了Fe2O3掺杂TiO2 (FDT)纳米粉体的热特性和介电特性。采用固相反应方法,用[1-x] TiO2 + [x] Fe2O3的分子式制备了FDT。采用原子力显微镜(AFM)技术对其表面形貌进行了研究;平均粒径在180 ~ 200nm之间。FT-IR分析表明,在1020 ~ 1650 cm-1和2800 ~ 3500 cm-1之间有较弱的透射带,随着Fe浓度的增加,透射峰强度逐渐降低。热稳定性采用热重分析(TGA)评价。TGA谱分析结果表明,FDT纳米粉体在400℃~ 600℃范围内热稳定。研究了该复合材料在室温下的介电性能与频率(20 Hz - 1 MHz)的关系,发现介电常数随频率的增加而减小,表明其具有色散特性。
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