A Simple Preparation Route to Palladium Nanoparticles Catalyst from Decomposition of Supported [Pd(lysine·HCl)(Cl)2] Complex

Hao Yu-zhi, Zhang Yu-long, Wang Li-hua, Ju Xiao-Yan
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引用次数: 1

Abstract

The supported palladium nanoparticles catalyst with uniform-sized Pd particles distribution and without nitro- gen or chlorine atoms present in catalyst was prepared by calcination of the supported (Pd(lysine·HCl)(Cl)2) complex as precursor and characterized by TEM. Moreover the supported (Pd(lysine·HCl)(Cl)2) complex was from cation exchanging (Pd(lysine·HCl)(Cl)2) complex with inorganic support. The hydrogenation characteristic of supported Pd nanoparticles catalyst was evaluated by using benzoic acid.
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负载型[Pd(赖氨酸·HCl)(Cl)2]配合物分解制备钯纳米颗粒催化剂的简单方法
以负载型(Pd(赖氨酸·盐酸)(Cl)2)配合物为前驱体,煅烧制备了尺寸均匀、不含氮和氯原子的负载型钯纳米催化剂,并用透射电镜对其进行了表征。Pd(赖氨酸·HCl)(Cl)2配合物是由Pd(赖氨酸·HCl)(Cl)2与无机载体阳离子交换形成的配合物。采用苯甲酸对负载型钯纳米催化剂的加氢特性进行了评价。
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