Hydrogen Permeation Property and Hydrogen Embrittlement Susceptibility of Pipeline Steel with Oxide Film

Shouzhuang Li, Weiming Zhao, Yong Wang
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引用次数: 1

Abstract

In this study, the oxide film on X80 steel was fabricated to decrease hydrogen embrittlement of pipeline steel. The microstructures and mechanical properties in 10MPa hydrogen gas and hydrogen permeation properties were investigated. The phase structure of oxide film was mainly composed of Fe2O3. With the increasing of oxidation temperature, surface oxygen content improves gradually. Oxide film plays an important role in resisting hydrogen penetrating. Hydrogen diffusion coefficient decreases from 38.81☓10-7cm2s-1 to 1.26☓10-7 cm2s-1 for oxidation at 450 ℃. The plastic deformation increases obviously after oxidation. HEI decreases from 40.96% to 11.61% for oxidation at 450 ℃.
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带氧化膜管道钢的氢渗透性能及氢脆敏感性
在X80钢表面制备氧化膜以降低管道钢的氢脆。研究了合金在10MPa氢气条件下的组织、力学性能和氢渗透性能。氧化膜的相结构以Fe2O3为主。随着氧化温度的升高,表面氧含量逐渐提高。氧化膜在抗氢渗透中起着重要的作用。450℃氧化时,氢的扩散系数从38.81 10-7cm2s-1降低到1.26 10-7cm2s-1。氧化后的塑性变形明显增大。450℃氧化后HEI由40.96%降至11.61%。
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