Adsorption of Acid Dye by Activated Carbon from Agricultural Solid Waste Leucona Leucocephala Seed Shell Waste: Kinetics, Equilibrium and Isotherm Study

Babu Rajendran A, K. S, P. R.
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引用次数: 1

Abstract

Activated carbons from Leucaena leucocephala Seed Shell left over were generated accompanied by 10% phosphoric acid solution in the N2 atmosphere by chemical activation and their characteristics were investigated. SEM, FTIR and XRD analysis were used to analyse the characteristics of the triggered preparations. Isothermal models, namely the Freundlich and Langmuir representations, were the equilibrium studies carried out.. The equilibrium adsorption result was better suited to the isotherm model of Langmuir and its maximum monolayer adsorption potential for acid blue was 70.67 mg/g. Adsorption kinetics studies have shown that the best fit is provided by the pseudo second-order dynamic model. An intraparticle dispersion model demonstrated that the dissemination of the intraparticle was not a step of rate control. Studies of thermodynamics have shown that the sorption mechanism is spontaneous and exothermic in nature. The findings suggest that the seed shells of Leucaena leucocephala may be used as a possible adsorbent for Acid blue1 adsorption.
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活性炭吸附农业固体白带种壳废渣中酸性染料的动力学、平衡及等温研究
采用10%磷酸溶液在N2气氛下化学活化法制备了银合子壳活性炭,并对其特性进行了研究。采用扫描电镜(SEM)、红外光谱(FTIR)和x射线衍射(XRD)分析了所制备的触发剂的特性。等温模型,即Freundlich和Langmuir表示,是进行的平衡研究。平衡吸附结果更符合Langmuir等温吸附模型,其对酸性蓝的最大单层吸附势为70.67 mg/g。吸附动力学研究表明,拟二阶动力学模型拟合效果最好。粒子内扩散模型表明,粒子内扩散不是速率控制的一个步骤。热力学研究表明,吸附机理是自发的、放热的。研究结果表明,银合子壳可作为一种吸附酸性蓝的吸附剂。
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