G. Clark, C. Reed, W. R. Roper, B. Skelton, T. Waters
{"title":"Four-co-ordinate iridium(I) cations and the ligand dependence of oxygen uptake: the crystal structure of [Ir(PPh2CH3)4]BF4","authors":"G. Clark, C. Reed, W. R. Roper, B. Skelton, T. Waters","doi":"10.1039/C29710000758","DOIUrl":null,"url":null,"abstract":"Four-co-ordinate iridium(I) cations containing various combinations of the ligands, CO, MeCN, Me2SO, PPh3, PPh2Me, and PPh2Et are described including an X-ray structural analysis of [Ir(PPh2Me)4]BF4: the ability of these cations to co-ordinate oxygen is found to be sensitive to steric factors.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"43 1","pages":"758-759"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"16","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000758","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 16
Abstract
Four-co-ordinate iridium(I) cations containing various combinations of the ligands, CO, MeCN, Me2SO, PPh3, PPh2Me, and PPh2Et are described including an X-ray structural analysis of [Ir(PPh2Me)4]BF4: the ability of these cations to co-ordinate oxygen is found to be sensitive to steric factors.
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