{"title":"Heat Dissipation at Cement Hardening","authors":"Z. Zhumadilova, K. Akmalaiuly","doi":"10.48141/SBJCHEM.V28.N28.2020.01_ZHUMADILOVA1_PGS_01_09.PDF","DOIUrl":null,"url":null,"abstract":"During the construction of concrete structures of small cross-sections, the release of heat during cement hardening has no harmful effects. With the increasing temperature of the hardening cement mass, the rate of cement hydration increases. This increases the rate of release of its heat of hydration of cement. The consequence of the accelerated process of hydration of the binder is a more intensive increase in the strength of cement stone than in the case of hardening under normal conditions. This fact is widely used in practice for the intensification of the hardening of concrete. When structures with small cross-sections are being built, the heat released during hardening is relatively quickly transferred to the surrounding space and does not cause a significant increase in temperature. In structures made of massive concrete (with a large cross-section), this heat is stored in the interior of the array for a long time, which causes a rather large rise in temperature and its slow drop. This is due to the fact that heat transfer to the external environment is hampered here by the considerable thickness of the massif and the rapid rate of concreting, mechanized laying of large masses of concrete. As a result, a temperature difference is created between the internal and external parts of the structure and harmful internal stresses arise that can cause cracking in the hardened concrete. This leads to a violation of its solidity. The faster cement hydrates, the sooner and more heat is released. The types of cements with a high content of tricalcium silicate and aluminate emit more heat and rather than types of cement with a high content of dicalcium silicate and tetra-calcium aluminoferrite. However, the latter has a lower strength. The increase in strength resulting from the hydration process is inevitably associated with the release of heat into the environment","PeriodicalId":20606,"journal":{"name":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2020-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.48141/SBJCHEM.V28.N28.2020.01_ZHUMADILOVA1_PGS_01_09.PDF","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1

Abstract

During the construction of concrete structures of small cross-sections, the release of heat during cement hardening has no harmful effects. With the increasing temperature of the hardening cement mass, the rate of cement hydration increases. This increases the rate of release of its heat of hydration of cement. The consequence of the accelerated process of hydration of the binder is a more intensive increase in the strength of cement stone than in the case of hardening under normal conditions. This fact is widely used in practice for the intensification of the hardening of concrete. When structures with small cross-sections are being built, the heat released during hardening is relatively quickly transferred to the surrounding space and does not cause a significant increase in temperature. In structures made of massive concrete (with a large cross-section), this heat is stored in the interior of the array for a long time, which causes a rather large rise in temperature and its slow drop. This is due to the fact that heat transfer to the external environment is hampered here by the considerable thickness of the massif and the rapid rate of concreting, mechanized laying of large masses of concrete. As a result, a temperature difference is created between the internal and external parts of the structure and harmful internal stresses arise that can cause cracking in the hardened concrete. This leads to a violation of its solidity. The faster cement hydrates, the sooner and more heat is released. The types of cements with a high content of tricalcium silicate and aluminate emit more heat and rather than types of cement with a high content of dicalcium silicate and tetra-calcium aluminoferrite. However, the latter has a lower strength. The increase in strength resulting from the hydration process is inevitably associated with the release of heat into the environment
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水泥硬化时的散热
在小截面混凝土结构施工中,水泥硬化过程中热量的释放没有有害影响。随着水泥体硬化温度的升高,水泥水化速率增大。这增加了水泥水化热的释放速度。胶结剂水化过程加速的结果是水泥石的强度比在正常条件下硬化的情况下更强烈的增加。这一事实在实践中被广泛用于混凝土硬化的强化。当建造小截面结构时,硬化过程中释放的热量相对较快地传递到周围空间,不会引起温度的显著升高。在由大块混凝土(具有大截面)制成的结构中,这些热量在阵列内部储存了很长时间,这导致了相当大的温度上升和缓慢下降。这是由于向外部环境的热量传递在这里受到相当厚的块体和混凝土的快速混凝土速度的阻碍,机械化铺设大块混凝土。结果,在结构的内部和外部部分之间产生温差,并且产生有害的内应力,可能导致硬化混凝土开裂。这就破坏了它的坚固性。水泥水化得越快,释放的热量也就越快。硅酸三钙和铝酸盐含量高的水泥比硅酸二钙和四钙铁铝酸盐含量高的水泥释放更多的热量。而后者的强度较低。由水化过程引起的强度的增加不可避免地与向环境中释放热量有关
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