Wolfgang A. Herrmann, Richard W. Fischer , João D.G. Correia
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引用次数: 79
Abstract
Methyltrioxorhenium CH3ReO3 (MTO, 1) is one of the most active catalysts of the Baeyer-Villiger oxidation of cyclic ketones by use of H2O2 as oxidant. In contrast to the chemistry of established molybdenum and tungsten peroxo complexes, the bis(peroxo) complex [CH3ReO(O2)2·H2O] reacts stoichiometrically with ketones. The electronic character of the active species was determined by spectroscopy and by application of an oxygen transfer probe.
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