The Preparation of Prussian Blue in a Mortar: An Example to Teach Sustainable Chemistry with Mechanochemical Reactions

A. Kraft
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Abstract

Solvent-free mechanochemical reactions represent an important path towards sustainable chemistry. The preparation of Prussian blue from solid iron and hexacyanoferrate compounds by the simple use of a mortar and pestle is an easy, inexpensive, and fast method to teach mechanochemical reactions. The course of the reaction can be followed very well visually via the color change of the solid mixture towards blue. With this communication, earlier publications on Prussian blue and mechanochemistry in the field of chemical education are updated and extended.
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在砂浆中制备普鲁士蓝:用机械化学反应教授可持续化学的一个例子
无溶剂机械化学反应是可持续化学的重要途径。用研钵和杵从固体铁和六氰高铁酸盐化合物中制备普鲁士蓝是一种简单、廉价、快速的机械化学反应教学方法。通过固体混合物向蓝色的颜色变化,可以很好地直观地跟踪反应的过程。有了这份通讯,化学教育领域关于普鲁士蓝和机械化学的早期出版物得到了更新和扩展。
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