CHAPTER 13. Baeyer–Villiger Oxidation Promoted by Noncovalent Interactions

Nuno M. R. Martins, L. Martins
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Abstract

The relative complexity of noncovalent interactions has made them challenging to study. Nevertheless, theory and modelling have now reached the stage that allows their physical origins to be explained and reliable insight to be gained into their effects on chemical transformations. This chapter discusses the influence of coordination and noncovalent interactions in Baeyer–Villiger oxidations. These attractive forces can be powerful tools in the formation/stabilization of intermediates and in controlling the product outcome of a reaction.
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第13章。非共价相互作用促进Baeyer-Villiger氧化
非共价相互作用的相对复杂性使得它们的研究具有挑战性。尽管如此,理论和模型现在已经达到了这样一个阶段,可以解释它们的物理起源,并对它们对化学转化的影响获得可靠的见解。本章讨论了配位和非共价相互作用在Baeyer-Villiger氧化中的影响。这些吸引力是形成/稳定中间体和控制反应产物的有力工具。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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