Synthesis, Properties of a New (Polymer and Chalcone)

M. Attia
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引用次数: 3

Abstract

This paper included two objectives: (i) Synthesis of Polymer {poly 2- [1- phenyl -3-(4-methyl phenyl)-4, 5-dihydropyrazole-5-yl-(4-phenoxy carbonyl)] styrene} PMDPCS and structure characterized by FT-IR, 1H-NMR spectra and Uv/Vis and XRD. (ii) Synthesis of chalcone {3-(4-(dimethylamino) phenyl)-2-phenyl-(2E) propen-1-one} (DAPPP) for absorption and fluorescence spectra under different solvents and concentrations.  Also, under various concentrations, organic solvents and pump pulse energies of Nd: YAG laser, the amplified spontaneous emission (ASE) was studied. Additionally, under the same identical conditions, the amplified spontaneous emission spectra of DAPPP in solution were compared with a conventional laser dye of coumarin 503. Finally, the gain and the fluorescence quantum yield of DAPPP were determined.
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一种新型聚合物及查尔酮的合成、性能
本文主要包括两个目的:(1)聚合物{聚2-[1-苯基-3-(4-甲基苯基)- 4,5 -二氢吡唑-5-基-(4-苯氧羰基)]苯乙烯}PMDPCS的合成及其结构的FT-IR、1H-NMR、Uv/Vis和XRD表征。(ii)合成查尔酮{3-(4-(二甲氨基)苯基)-2-苯基-(2E)丙烯-1- 1}(DAPPP),测定不同溶剂和浓度下的吸收光谱和荧光光谱。在不同浓度、有机溶剂和泵浦脉冲能量下,研究了Nd: YAG激光的放大自发发射(ASE)。此外,在相同条件下,比较了DAPPP与香豆素503激光染料在溶液中的放大自发发射光谱。最后测定了DAPPP的增益和荧光量子产率。
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