Crystal Structure of a Novel Coordination Polymer of 4-Bromobenzoic Acid with Cobalt(II)

X. Qiu, Weisheng Liu, Hailiang Zhu
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引用次数: 2

Abstract

A novel coordination polymer of cobalt(II) with 4-bromobenzoic acid ligand was synthesized. The title complex was crystallized in a monoclinic system, space group P21/n with a = 15.396(3)A, b = 5.8802(12)A, c = 27.374(6)A, β = 101.16(3)°, V = 2431.4(9)A3, Z = 4. The central Co(II) atoms are six-coordinated by four O atoms and two N atoms, giving approximately octahedral environments. In the crystal packing of the title complex, molecules are connected by O-H…O hydrogen bonds, forming a linear polymeric chain parallel along the b axis.
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新型4-溴苯甲酸-钴配位聚合物的晶体结构
合成了一种新型的4-溴苯甲酸配体钴(II)配位聚合物。标题配合物在单斜晶系中结晶,空间群为P21/n, a = 15.396(3) a, b = 5.8802(12) a, c = 27.374(6) a, β = 101.16(3)°,V = 2431.4(9)A3, Z = 4。中心Co(II)原子由四个O原子和两个N原子六配位,形成近似八面体环境。在标题配合物的晶体包装中,分子由O- h…O氢键连接,形成沿b轴平行的线性聚合链。
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