Storage of CO2 and Coal Fly Ash using Pickering Foam for Enhanced Oil Recovery

Abstract

CO2 foams have been used for a long time for enhanced oil recovery (EOR) and carbon capture, utilization, and storage. Note that conventional CO2 foam focuses on mobility control and storage of bare CO2. However, this technology has suffered from low storage efficiency and EOR because of foam instability. In this study, the geological storage of CO2 and coal fly ash (CFA) using Pickering foam for EOR was explored. The aim is to obtain an inexpensive method for EOR and storage of greenhouse gases and atmospheric pollutants. The Pickering foam was prepared using Waring blender method. The experiments were conducted to evaluate CO2/liquid interface enhancement by measuring the interfacial tension and interfacial viscoelastic modulus. As per the heterogeneous sandpack flooding experiments, the profile control capacity and the performance of oil displacement using CO2 foam enhanced by CFA were investigated. The amount of storage from dynamic aspects of CO2 and CFA was measured to demonstrate the storage law. The stability of aqueous foam was improved significantly after the addition of CFA. The half-life time of foam stabilized by CFA particles increased by more than about 11 times than that of foam without CFA particles. The interfacial dilatational viscoelastic modulus of CO2/foaming solution increased with CFA particle concentration increasing, indicating the interface transformed from liquid-like to solid-like. Flooding experiments in heterogeneous porous media showed that more produced fluid was displaced from the relatively low-permeability sandpack after the injection of CO2 foam with CFA. The oil recovery by CFA stabilized foam was improved by ~28.3% than that of foam without CFA particles. And the sequestration of CO2 in heterogeneous porous media was enhanced with the addition of CFA to CO2 foam, and the CFA stabilized foam displayed a strong resistance to water erosion for the storage of CO2 and CFA. This work introduces a win–win method for EOR and storage of CO2 and atmospheric pollutant particles. CFA from coal combustion was used as an enhancer for CO2 foam, which improved the interfacial dilatational viscoelasticity of foam film and the dynamic storage of CO2. Furthermore, the storage of CO2 and CFA contributed to improvement in sweep efficiency, and thus EOR.