Chemisorptive catalytic oxidation process for SO2 from smelting waste gases by Fe(II)

Hans-Jörg Bart , Ping Ning , Peishi Sun , Wenpiao Song
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引用次数: 2

Abstract

Chemisorption of SO2 from smelting plant exhaust gases in a single sieve plate column was investigated. Main parameters were SO2 and O2 gas and H2SO4, FeSO4 and Al2(SO4)3 liquid concentrations on reaction rate and equilibrium in FeII-EDTA solutions. Absence of inhibitors with this kind of flue gases promote fast kinetics. Optimal process conditions with 3% wt. FeSO4 catalyst up to 2000 PPM SO2. Maximum yield of 16% H2SO4 could be achieved considering optimal liquid/vapor ratio, oxygen surplus and insert salt concentrations.

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Fe(II)化学吸附催化氧化冶炼废气中SO2的研究
研究了单筛板塔对冶炼厂废气中二氧化硫的化学吸附。主要参数为SO2和O2气体以及H2SO4、FeSO4和Al2(SO4)3液体浓度对fei - edta溶液中反应速率和平衡的影响。这种烟气中不含抑制剂可促进快速动力学。最佳工艺条件为3%重量的FeSO4催化剂,最高可达2000 PPM SO2。考虑最佳液汽比、剩余氧和插入盐浓度,H2SO4产率最高可达16%。
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