Pingping Zhou, Xiaohui Li, Yanli Dong, Hui-min Liu
{"title":"Synthesis, Structure and Photoluminescent Properties of a New Ba(II)-Doped Cd(II) Coordination Polymer","authors":"Pingping Zhou, Xiaohui Li, Yanli Dong, Hui-min Liu","doi":"10.1080/15533174.2014.989587","DOIUrl":null,"url":null,"abstract":"A new heterometallic compound, namely [CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-thiophenedicarboxylic acid, DMF = N,N′-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework based on heterometallic -{Cd-COO-Ba}n- inorganic chains. In addition, the luminescent properties of this compound were also investigated at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.989587","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
A new heterometallic compound, namely [CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-thiophenedicarboxylic acid, DMF = N,N′-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework based on heterometallic -{Cd-COO-Ba}n- inorganic chains. In addition, the luminescent properties of this compound were also investigated at room temperature.
采用溶剂热法合成了一种新的杂金属化合物[CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-噻吩二羧酸,DMF = n, n ' -二甲基甲酰胺),并用元素分析和x射线单晶衍射对其进行了表征。化合物1具有基于杂金属-{Cd-COO-Ba}n-无机链的复杂三维(3D)结构。此外,还研究了该化合物在室温下的发光性能。