Synthesis and spectroscopic properties of LiIn(WO4)2 nanopowders and single crystals doped with chromium(III) ions

T. Skibiński, H. Fuks, S. Kaczmarek, T. Bodziony, K. Hermanowicz, M. Ma̧czka, M. Ptak, J. Hanuza
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引用次数: 1

Abstract

LiIn(WO4)2 single crystals and nanopowders doped with chromium(III) ions were synthesized and investigated, including their EPR spectra and magnetic properties. The EPR spectra have shown low and high field lines attributed to isolated chromium ions with an electron spin S=3/2 and complex chromium centers with higher spin value, respectively. Magnetic susceptibility measurements revealed an almost linear dependence on the magnetic field. The electron resonance and magnetic properties have been related to the structural and spectroscopic data of the studied material.
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掺杂铬(III)离子的LiIn(WO4)2纳米粉体及单晶的合成与光谱性质
合成了掺杂铬(III)离子的LiIn(WO4)2单晶和纳米粉体,并对其EPR谱和磁性能进行了研究。EPR谱分别显示了电子自旋为S=3/2的孤立铬离子和具有较高自旋值的络合铬中心的低场线和高场线。磁化率测量结果显示,磁化率与磁场几乎呈线性关系。电子共振和磁性能与所研究材料的结构和光谱数据有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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Central European Journal of Physics
Central European Journal of Physics 物理-物理:综合
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3.3 months
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