Notice of RetractionPreparation of Cyanamide by Decomposition of Urea

Liu Yan, Lv Shuxiang
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Abstract

The paper mainly studies a new preparation technology of cyanamide. The auther designs a new technology: urea-cyanamide method. Different catalysts were used in the technoloy: ZSM-5 zeolite which are doped with transition metal cations selected from the Group A and Group B. The prepared catalysts were used in the decomposition of urea. Reaction conditions were as followed: with certain reaction temperature, reaction time, certain amount of catalyst, in the atmosphere of ammonia, so that the urea was decomposited into Cyanamide under normal pressure. This technology confirms atomic economical principle and it is low energy-consuming with little pollution and simple refining technology. Therefore it is a technology with good social and economic benefit. The difficulty of urea-cyanamide method is the selection of catalyst and high requirements for equipment.
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回收尿素分解法制备氰胺的通知
本文主要研究了一种新的氰酰胺制备工艺。设计了一种新工艺:尿素-氰酰胺法。该工艺采用不同的催化剂:ZSM-5沸石分别掺杂A族和b族过渡金属阳离子,制备的催化剂用于尿素的分解。反应条件为:在一定的反应温度、反应时间、一定的催化剂用量下,在氨气中,使尿素在常压下分解成氰酰胺。该工艺证实了原子经济原理,能耗低,污染少,精炼工艺简单。因此,它是一项具有良好社会效益和经济效益的技术。尿素-氰酰胺法的难点在于催化剂的选择和对设备的要求高。
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