Boson Peak and Fracton of Sodium Carboxymethyl Starch Detected by Terahertz Time-Domain and Low-Frequency Raman Spectroscopies

Wakana Terao, Tatsuya Mori, Seiji Koiima, K. Kaczmarska, B. Grabowska, Y. Fujii, A. Koreeda, J. Ko
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Abstract

We performed terahertz time-domain spectroscopy and low-frequency Raman scattering on microwave-treated carboxymethyl starch (CMS-Na), to detect universal boson peak (BP) behavior in glassy materials and fracton which is expected to universally appear in polymer glass. The obtained spectral shape of BP plot a(v)/v2of the CMS-Na-slu, where a(v) is the absorption coefficient, is different from either starch or vitreous glucose of the previous study. It suggests that existence of the fracton in the CMS-Na-slu.
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太赫兹时域和低频拉曼光谱检测羧甲基淀粉钠的玻色子峰和分数
我们对微波处理的羧甲基淀粉(CMS-Na)进行了太赫兹时域光谱和低频拉曼散射,以检测玻璃材料和聚合物玻璃中普遍存在的分数的通用玻色子峰(BP)行为。得到的CMS-Na-slu的BP图a(v)/v2的光谱形状,其中a(v)为吸收系数,不同于之前研究的淀粉或玻璃体葡萄糖。表明该分型存在于CMS-Na-slu中。
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