Zhuo-wen Fan, Long Li, K. Cui, Shuangbing Yang, Fusan Han
{"title":"Structure and Luminescent Property of a New Cd(II) Coordination Polymer With (3,6)-Connected ant Topology","authors":"Zhuo-wen Fan, Long Li, K. Cui, Shuangbing Yang, Fusan Han","doi":"10.1080/15533174.2015.1136962","DOIUrl":null,"url":null,"abstract":"Solvothermal reactions of Cd(NO3)2, H3btc, and HBTA afforded a new Cd(II) compound, namely (NH3)2[Cd3(btc)2(BTA)(DMA)]n (1 H3btc = 1,3,5-benzenetricarboxylic acid, HBTA = 1,2,3- benzenetriazole, DMA = N, N′-dimethylacetamide). Single-crystal X-ray analysis reveals that 1 is a complicated three-dimensional (3D) framework based on benzotriazole-controlled trinuclear Cd(II) clusters, which can be simplified into a (3,6)-connected ant-type topological network. Moreover, the luminescent properties of this compound were also investigated at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1136962","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
Solvothermal reactions of Cd(NO3)2, H3btc, and HBTA afforded a new Cd(II) compound, namely (NH3)2[Cd3(btc)2(BTA)(DMA)]n (1 H3btc = 1,3,5-benzenetricarboxylic acid, HBTA = 1,2,3- benzenetriazole, DMA = N, N′-dimethylacetamide). Single-crystal X-ray analysis reveals that 1 is a complicated three-dimensional (3D) framework based on benzotriazole-controlled trinuclear Cd(II) clusters, which can be simplified into a (3,6)-connected ant-type topological network. Moreover, the luminescent properties of this compound were also investigated at room temperature.
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