CHAPTER 7. The Role of Noncovalent Interactions in the Efficiency of Dendrimers in Catalysis

A. Caminade
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引用次数: 1

Abstract

Dendrimers are nanometric macromolecules constituted of repetitive branched units, arranged radially around a central core. They are synthesized step-by-step, generally using a divergent process from this core. Dendrimers have many properties and, among them, catalysis is a major field. Two main area are studied, on the one hand the search for a positive “dendrimer effect,” i.e. an increase in catalytic efficiency when the size of the dendrimer increases, and on the other the encapsulation of catalytically active nanoparticles inside dendrimers. In both cases, noncovalent interactions are involved. This chapter discusses the important role played by noncovalent interactions in the properties of dendrimers in catalysis. The first part concerns the dendrimer effect, then a short section considers noncovalently formed catalytic dendrimers and the final part concerns dendrimers encapsulating catalytic nanoparticles.
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第七章。非共价相互作用在树状大分子催化效率中的作用
树状大分子是由重复的分支单位组成的纳米大分子,围绕中心核呈放射状排列。它们是一步一步合成的,通常使用从这个核心发散出来的过程。树状大分子具有许多性质,其中催化作用是一个主要领域。研究的两个主要领域,一方面是寻找积极的“树状大分子效应”,即当树状大分子的尺寸增加时催化效率的增加,另一方面是在树状大分子内部封装催化活性纳米颗粒。在这两种情况下,都涉及非共价相互作用。本章讨论了非共价相互作用在树状大分子催化性能中的重要作用。第一部分关注树状大分子效应,然后一小部分考虑非共价形成的催化树状大分子,最后一部分关注包裹催化纳米颗粒的树状大分子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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