A study of synthesizing benzaldehydes from propenylbenzenes and cinnamic acid derivatives

Maw-Ling Wang, Venugopal Rajendran
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引用次数: 4

Abstract

Propenylbenzenes and cinnamic acid derivatives yield correspondingly substituted benzaldehydes when oxidized by lead-ruthenium pyrochlore oxide in the presence of sodium hydrochlorite as a co-oxidant at pH 11 under heterogeneous conditions. The reaction of terminal and internal aliphatic alkenes under similar conditions affords no aldehydes.

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丙烯苯与肉桂酸衍生物合成苯甲醛的研究
丙烯苯和肉桂酸衍生物在pH为11的非均相条件下,在盐酸钠作为共氧化剂的情况下,用焦氯酸铅钌氧化产生相应的取代苯甲醛。末端和内部脂肪烯烃在类似条件下的反应不产生醛。
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