Thermodynamics and spectroscopic properties of N-methylpiperazine with propan-1-ol, 2-propen-1-ol, 2-propyn-1-ol

Abstract

ABSTRACT The density (ρ), viscosity (η), and speed of sound (u) are reported for binary mixtures of N-methylpiperazine with aliphatic primary alcohols (propan-1-ol, 2-propen-1-ol, 2-propyn-1-ol) over the entire composition range from 303.15 K to 313.15 K and at atmospheric pressure 0.1 MPa. The excess parameters (VE,κs E), deviation in viscosity, and excess partial properties ( , and ) of the components at infinite dilution were calculated from the density, speed of sound, and viscosity at experimental temperatures. All the investigated systems exhibit positive values of ∆η and ∆G *E and negative values of VE and κs E over the whole composition range. The obvious deviations attribute to the association between the primary alcohols and N-methyl piperazine molecules through the hydrogen bond of O-H· · ·N. A good agreement is obtained between excess quantities and FTIR spectroscopic data.