The Catalytic Hydrogenolysis of Esters to Alcohols

IF 9.3 2区 化学 Q1 CHEMISTRY, PHYSICAL Catalysis Reviews-Science and Engineering Pub Date : 1994-11-01 DOI:10.1080/01614949408013931
T. Turek, D. Trimm, N. W. Cant
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引用次数: 191

Abstract

Abstract The hydrogenolysis of esters to alcohols is a reaction between esters and hydrogen which selectively splits a C-0 bond adjacent to a carbonyl group (1). A well-known large-scale industrial process based on this reaction the production of fatty alcohols from natural fatty acid esters-has been operated commercially for more than 50 years. Several processes which include the hydrogenolysis of an ester have been proposed for the manufacture of basic chemicals such as methanol and ethanol. Furthermore, there has been continuous interest over the past two decades in replacing the existing, energy-intensive processes for the production of ethylene glycol and 1,4-butanedioI by more cost-effective routes involving ester hydrogenolysis. While particular aspects of the literature on hydrogenolysis of esters have been reviewed already [1–3], the objective of the present work is to give a more general summary with special emphasis on the present or possible industrial applications of ester hydrogenolysis.
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酯类催化氢解制醇
酯氢解制醇是酯和氢选择性分裂羰基附近的C-0键的反应(1)。基于该反应的一个众所周知的大规模工业过程——从天然脂肪酸酯中生产脂肪醇——已经在商业上运行了50多年。已经提出了几种方法,其中包括酯的氢解,用于制造基本化学品,如甲醇和乙醇。此外,在过去的二十年里,人们一直对用更具成本效益的酯氢解方法取代现有的生产乙二醇和1,4-丁二醇的能源密集型工艺感兴趣。虽然已经对酯类氢解的特定方面的文献进行了综述[1-3],但本工作的目的是对酯类氢解目前或可能的工业应用进行更全面的总结。
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来源期刊
CiteScore
22.30
自引率
2.80%
发文量
29
期刊介绍: Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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