{"title":"Formation of a cationic binuclear iron–dinitrogen compound from molecular nitrogen","authors":"W. Silverthorn","doi":"10.1039/C29710001310","DOIUrl":null,"url":null,"abstract":"Treatment of the compound π-C5H5Fe(dmpe)I (dmpe = Me2PCH2CH2PMe2) in acetone with TlBF4 and nitrogen gas yields the binuclear dinitrogen complex {[π–C5H5Fe(dmpe)]2N2}2+(BF4–)2, 2H2O which readily reacts with carbon monoxide and LiAlH4 giving the complexes [π–C5H5Fe(dmpe)CO]+BF4– and π–C5H5Fe(dmpe)H, respectively.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"114 1","pages":"1310-1311"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"20","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001310","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 20
Abstract
Treatment of the compound π-C5H5Fe(dmpe)I (dmpe = Me2PCH2CH2PMe2) in acetone with TlBF4 and nitrogen gas yields the binuclear dinitrogen complex {[π–C5H5Fe(dmpe)]2N2}2+(BF4–)2, 2H2O which readily reacts with carbon monoxide and LiAlH4 giving the complexes [π–C5H5Fe(dmpe)CO]+BF4– and π–C5H5Fe(dmpe)H, respectively.
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