Thermodynamics and kinetics of adsorption in the presence of geometric roughness

Massimiliano Giona , Manuela Giustiniani
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引用次数: 5

Abstract

We analyze in detail the thermodynamic properties and the kinetic features of adsorption on fractal structures, focusing on those topics that can be useful in practical adsorption-based processes and highlighting the theoretical results that can be applied in the design of suitable separation and sorption conditions. The development and the application of thermodynamically consistent models of adsorption isotherms, encompassing the fractality of the adsorbent and the volume-to-surface effects in microporous fractal structures, are analyzed.

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几何粗糙度下吸附的热力学和动力学
我们详细分析了分形结构上吸附的热力学性质和动力学特征,重点讨论了在实际吸附过程中有用的问题,并强调了可以应用于设计合适的分离和吸附条件的理论结果。分析了吸附等温线的热力学一致模型的发展和应用,包括吸附剂的分形和微孔分形结构中的体积-表面效应。
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