Crystal Structure of a Novel Coordination Polymer of 2-Hydroxy-N′-(propan-2-ylidene)benzohydrazide with Cadmium(II)

X. Qiu, Weisheng Liu, Hailiang Zhu
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Abstract

A novel coordination polymer of cadmium(II) with 2-hydroxy-N′-(propan-2-ylidene)benzohydrazide was synthesized and the structure was characterized by X-ray analysis. The title complex was crystallized in a monoclinic system, space group C2/c with a = 12.4693(8)A, b = 8.9986(8)A, c = 21.6986(18)A, β = 99.480(2)°, V = 2401.5(3)A3, Z = 4. The central Cd(II) atoms are six-coordinated by four O atoms and two N atoms, giving approximately octahedral environments. In the crystal packing of the title complex, molecules are connected by intramolecular O-H…N and intermolecular O-H…O hydrogen bonds, forming a two-dimensional layer parallel to the ab plane.
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新型2-羟基- n′-(丙-2-酰基)苯并肼与镉(II)配位聚合物的晶体结构
合成了一种新型镉(II)与2-羟基- n′-(丙烷-2-酰基)苯并肼配位聚合物,并用x射线分析对其结构进行了表征。该配合物在C2/c单斜晶系中结晶,空间群a = 12.4693(8) a, b = 8.9986(8) a, c = 21.6986(18) a, β = 99.480(2)°,V = 2401.5(3)A3, Z = 4。中心的Cd(II)原子由四个O原子和两个N原子六配位,形成近似八面体环境。在标题配合物的晶体填料中,分子通过分子内的O- h…N和分子间的O- h…O氢键连接,形成平行于ab平面的二维层。
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