The effect of orthophosphoric acid on energy-intensive parameters of porous carbon electrode materials.

IF 0.9 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Solid State Pub Date : 2023-02-23 DOI:10.15330/pcss.24.1.34-45
N. Ivanichok, P. Kolkovskyi, A. Soltys, V. Boychuk, V. Mandzyuk, L. Yablon, B. Rachiy
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引用次数: 1

Abstract

The effect of orthophosphoric acid concentration as an activating agent on the porous structure of carbon materials derived from apricot pits and energy-intensive parameters of electrochemical capacitors formed on their basis is studied. It is found that changing the ratio of the mass of the activating agent to the mass of the raw material in acid-activated porous carbon materials (PCMs), one can control the pore size distribution in the range of 0.5-20 nm and specific surface area in the range of 775-1830 m2/g. The use of cyclic voltammetry, impedance spectroscopy and chronopotentiometry made it possible to set the capacitive nature of charge accumulation processes in acid-activated PCMs, as well as to determine the contribution of a certain size of pores to the specific capacitance of PCM/electrolyte system.
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正磷酸对多孔碳电极材料耗能参数的影响。
研究了正磷酸浓度作为活化剂对杏核炭材料多孔结构及在其基础上形成的电化学电容器耗能参数的影响。研究发现,在酸活化多孔炭材料(PCMs)中,改变活化剂质量与原料质量的比例,可以将其孔径分布控制在0.5 ~ 20 nm范围内,比表面积控制在775 ~ 1830 m2/g范围内。利用循环伏安法、阻抗谱法和时电位法,可以设定酸活化PCM中电荷积累过程的电容性质,并确定一定尺寸的孔隙对PCM/电解质体系比电容的贡献。
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来源期刊
CiteScore
1.70
自引率
14.30%
发文量
83
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