Effects of Salts and pH on the Emulsion Stabilities of Digalactosylmonoacylglycerol and Trigalactosylmonoacylglycerol

T. Nakae, T. Kometani, T. Nishimura, H. Takii, S. Okada
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Abstract

The effects of salts and pH on the emulsion stabilities of water/kerosene (1:1, w/w) emulsions prepared with digalactosylmonoacylglycerol (DGMG) and trigalactosylmonoacylglycerol (TGMG) were investigated. The creaming stabilities of the emulsions prepared with 0.05% DGMG and TGMG did not change up to 0.2 M CaCl2, and their medium droplet sizes were constant. The creaming stabilities of their emulsions with salts were higher, and the medium droplet sizes of their emulsions were smaller than those of the sucrose esters of fatty acids and lysolecithin. The ratio of the oil phase weight to total weight separated by centrifuging the DGMG and TGMG emulsions were constant up to 0.2 M CaCl2, and were smaller than those of the sucrose esters of fatty acids and lysolecithin. The creaming stabilities of the emulsions prepared with 0.05% DGMG and TGMG did not change with various pHs, and their medium droplet sizes were constant. The creaming stabilities of their emulsions in an acidic pH were higher than those of the sucrose esters of fatty acids. The oil phase separation by centrifuging the DGMG and TGMG emulsions were constant at various pHs.
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盐和pH对双半乳糖单酰甘油和三半乳糖单酰甘油乳液稳定性的影响
研究了盐和pH对双半乳糖单酰基甘油(DGMG)和三半乳糖单酰基甘油(TGMG)制备水煤油(1:1,w/w)乳液稳定性的影响。0.05% DGMG和TGMG制备的乳剂的乳化稳定性在0.2 M CaCl2下没有变化,且其介质液滴大小不变。它们的乳剂与盐的乳化稳定性较高,乳剂的中滴尺寸小于脂肪酸蔗糖酯和溶卵磷脂的中滴尺寸。经离心分离的DGMG和TGMG乳状液的油相质量与总质量之比在0.2 M CaCl2时保持不变,且小于脂肪酸蔗糖酯和溶卵磷脂的油相质量。0.05% DGMG和TGMG制备的乳剂的成乳稳定性不随ph值的变化而变化,其介质液滴大小不变。它们的乳剂在酸性pH值下的乳化稳定性高于脂肪酸的蔗糖酯。在不同ph值下,DGMG和TGMG乳状液的油相分离是恒定的。
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