{"title":"Rhodium(II) carboxylates","authors":"T. Ho, M. Fieser, L. Fieser, R. Danheiser, W. Roush, Janice Y. Smith","doi":"10.1002/9780471264194.fos08768.pub2","DOIUrl":null,"url":null,"abstract":"This article has no abstract. \n \nKeywords: \n \ncyclopropanation with alkyl diazoacetates; \ncyclopropenation; \nthiophenium ylides; \ncyclopropanation; \nβ-lactams; \nβ-keto esters from α-diazo-β-hydroxy esters; \nbuchner reaction; \ncyclopropanation of ; \n2-carbapenems; \nalkylation of β-lactams; \nintramolecular cycloaddition of a diazo ketone to a cyclopropene; \ncyclopentanones; \ncis-α,β-unsaturated esters; \nunsaturated ethers; \nδ-lactones; \nchiral cyclopentanones; \nintramolecular buchner reaction; \nhydroformylation; \nbenzyl ketones; \ncyclization-cycloaddition of an α-diazoacetophenone; \nchiral 3,3-disubstituted cyclopentanones; \nintramolecular C—H insertion; \noxepanes and oxocanes; \ncyclopropanation of furanyl diazo ketones; \nβ-lactams; \nα-silyl esters or ketones; \ndiazo ketone cyclization to hydroazulenones; \ncyclization/cycloaddition route to oxapolycycles; \n2,5-disubstituted 3(2H)-furanones; \nfurans; \ncarbenoid–monothiophthalimide coupling; \nrearrangement of N-nitrosoamides; \ntropones; \nreaction of α-diazo ketones with alkynes; \nsynthesis of (+)-griseofulvin (3); \nreaction of cyclic diazo-1,3-dicarbonyls with aryl heterocycles; \ntricyclic dihydropyrrolizines; \nreaction with cyclopropenes; \nα-alkoxy esters; \ninsertion into SiH bonds; \nheterocyclization; \nsilylformylation; \ncarbenoid insertions; \ncyclopropanation; \nheterocycles; \nconjugated ketenes; \nhydroformylation; \ncarbenoid insertions; \nrearrangements; \nfour-membered rings; \ndiheterobicycloalkanes; \n[3 + 2]cycloadditions; \nwolff rearrangement; \nthree-membered rings; \nfive-membered rings; \nC-H insertion; \nrearrangement; \n1-acetoxyazulenes; \ncoupling; \ntransylidation; \nbond insertion; \nbicyclization; \nbenzyl alcohols; \nN-sulfonylcarboxamides; \nisomerization; \narylation; \nCH Bond Insertion; \nNH Bond Insertion; \nNO Bond Insertion; \ncyclization; \nrhenium(VII) oxide; \nRh/alumina catalyst hydrogenation; \nrhodium - iron; \nrhodium(I) hexafluoroantimonate; \nruthenium(III) chloride hydrate","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":"68 1","pages":"000-000"},"PeriodicalIF":0.0000,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fieser and Fieser's Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780471264194.fos08768.pub2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
铑(II)羧化物
这篇文章没有摘要。关键词:烷基重氮乙酸酯环丙烷化;cyclopropenation;thiophenium内鎓盐;摘要总结;β-lactams;α-重氮-β-羟基酯生成的β-酮酯;毕希纳反应;环丙烷化;2-carbapenems;β-内酰胺的烷基化反应;重氮酮与环丙烯的分子内环加成环戊酮;顺式-α,β不饱和酯;不饱和醚;δ内酯;手性环戊酮;分子内buchner反应;加氢甲酰化;苄基酮;环化- α-重氮苯乙酮的环加成反应手性3,3-二取代环戊酮;分子内碳氢键插入;氧烷和氧烷;呋喃基重氮酮的环丙烷化反应β-lactams;α-硅酯或酮;重氮酮环化制备氢偶氮酮氧多环的环化/环加成途径;2, 5-disubstituted 3 (2 h) -furanones;呋喃;carbenoid-monothiophthalimide耦合;n -亚硝基酰胺重排;环庚三烯酮;α-重氮酮与炔烃的反应(+)-灰黄霉素(3)的合成环重氮-1,3-二羰基与芳基杂环的反应三环dihydropyrrolizines;与环丙烯的反应;α烷氧基酯;插入到SiH键;heterocyclization;silylformylation;carbenoid插入;摘要总结;杂环化合物;共轭烯酮;加氢甲酰化;carbenoid插入;重组;四元环;diheterobicycloalkanes;[3 + 2]环加成;沃尔夫重排;三元环;五元环;碳氢键插入;重排;1-acetoxyazulenes;耦合;transylidation;债券插入;bicyclization;苄醇;N-sulfonylcarboxamides;异构化;芳基化;CH键插入;NH键插入;无键插入;环化;铼(七)氧化;Rh/氧化铝催化剂加氢;铑-铁;铑锑酸(I);水合氯化钌
本文章由计算机程序翻译,如有差异,请以英文原文为准。