Surface modification of ABS polymer by electroless deposition of thin nickel film from a solution without reducing agent

V. Chakarova, M. Petrova, E. Dobreva, D. Lazarova, M. Monev
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Abstract

ABSTRACT For preparation of acrylonitrile–butadiene-styrene (ABS) polymer, suitable for electrodeposition of a subsequent metal coating, a modification of the activated polymer surface by electroless nickel deposition in an alkaline nickel citrate-based solution without reducing agent is proposed. The influence of the main components of the solution and the working conditions on the mass of the nickel deposit has been studied. The modified surface was characterised using SEM, EDS and XPS analyses. The obtained nickel in oxidised state is sufficient to conduct current for subsequent electrodeposition of copper coating.
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用无还原剂溶液化学沉积镍薄膜对ABS聚合物进行表面改性
摘要:为了制备适合电沉积后续金属涂层的ABS聚合物,提出了在碱性柠檬酸镍基溶液中无还原剂化学镀镍对活性聚合物表面进行改性的方法。研究了溶液的主要成分和工作条件对镍镀层质量的影响。用SEM、EDS和XPS对改性后的表面进行了表征。得到的氧化态镍足以为后续的铜镀层电沉积提供电流。
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