Experiments on the Electron Impact Excitation of Hydrogen Molecules Indicate the Presence of the Second Flavor of Hydrogen Atoms

Abstract

In one of our previous papers, we performed a comparative analysis of the experimental and theoretical cross-sections for the excitation of atomic hydrogen by electrons. We found that the theoretical ratio of the cross-section σ2s of the excitation of the state 2s to the cross-section σ2p of the excitation of the state 2p was systematically higher than the corresponding experimental ratio by about 20% (far beyond the experimental error margins). We showed that this discrepancy can be due to the presence of the Second Flavor of Hydrogen Atoms (SFHA) in the experimental gas and that the share of the SFHA in the mixture, required for removing this discrepancy, was about the same as the share of the usual hydrogen atoms. The theory behind the SFHA was based on the standard quantum mechanics—on the second solution of the Dirac equation for hydrogen atoms—and on the experimental fact that the charge distribution inside the proton has the peak at the center of the proton; the term “flavor” was used by the analogy with flavors of quarks. In the present paper, we used the same guiding principles, as employed in that previous study, for the comparative analysis of the experimental and theoretical cross-sections for the excitation of molecular hydrogen by electrons. We found that presumably the most sophisticated calculations, using the convergent close-coupling method involving 491 states, very significantly underestimate the corresponding experimental cross-sections for the two lowest stable triplet states. We showed that if in some hydrogen molecules one or both atoms would be the SFHA, then the above very significant discrepancy could be eliminated. We estimated that it would take such unusual hydrogen molecules to be represented in the experimental gas by the share of about 0.26. This is just by about 40% smaller than the share 0.45 of the SFHA deduced in our previous analysis of the experiment on the electron impact excitation of hydrogen atoms (rather than hydrogen molecules). It should be emphasized that from the theoretical point of view, the share of the unusual hydrogen molecules in any experimental gas and the share of the unusual hydrogen atoms (SFHA) in any experimental gas should not be expected to coincide (it would be the comparison of “apples to oranges”, rather than “apples to apples”). In addition, given the roughness of the above estimates, we can state that the results of the present paper reinforce the main conclusion of our previous papers of the very significant share of the SFHA in the experimental hydrogen gases. Thus, the experiments on the electron impact excitation of hydrogen molecules are the fourth type of atomic experiments that proved the existence of the SFHA.