Application of thermal destruction processes for recycling of polymer waste

S. F. Valeev, F. R. Zainullov, A. Sulimov, M. V. Zheleznov
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Abstract

A comprehensive study of thermal destruction of household and industrial polymeric materials wastes by the thermolysis method was carried out on the pilot plant. A mixture containing polyethylene, polypropylene, polystyrene and polyethylene terephthalate was considered as household polymeric waste. Individual industrial waste was represented by polyethylene, polypropylene and polystyrene. The influence of the composition of polymer waste, the temperature of the thermolysis process on the yield of gaseous and liquid products has been studied. A detailed analysis of the resulting products was carried out, their qualitative and quantitative composition was investigated. It was found that the change in temperature, duration of thermal processing, as well as the nature of polymer waste, allows us to control the composition and quality of the resulting products. The negative role of processing additives at the stage of polymer recycling is noted. It is shown that the thermolysis process is an effective tool for recycling polymer waste.
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热破坏工艺在聚合物废料回收中的应用
在中试装置上对家用和工业用高分子材料废弃物的热分解进行了综合研究。含有聚乙烯、聚丙烯、聚苯乙烯和聚对苯二甲酸乙二醇酯的混合物被认为是生活聚合物废物。个别工业废弃物以聚乙烯、聚丙烯和聚苯乙烯为代表。研究了废聚合物的组成、热裂解温度对气液产物收率的影响。对所得产物进行了详细的分析,并对其定性和定量组成进行了研究。结果发现,温度的变化,热处理的持续时间,以及聚合物废料的性质,使我们能够控制最终产品的成分和质量。指出了加工助剂在聚合物回收阶段的消极作用。结果表明,热裂解工艺是回收废旧高分子材料的有效手段。
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