Catalytic Methods for the Production of Sugar Esters

Monday Abel Otache, R. Duru, O. Achugasim, O. Abayeh
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Abstract

Nowadays, Sugar esters (SEs) have become the focus of researchers due to their biocompatibility and extensive industrial applications as surfactants. This trend provides new methods and opportunities for the development of green synthetic chemistry. Taking the above into consideration, a critical review presented in this work emphasized the efficiency of catalyzing the synthesis of SEs with minimal hazardous by-products. These catalytic media have been employed with various impacts involving chemical, biological, and other catalytic materials. Chemical methods have been reported to show limitations in terms of preparation and bio-compatibility. To solve these shortcomings, therefore, other technologies have been adopted; ionic liquids (eutectic solvents), chemo-enzymatic systems and chemo-enzymatic systems on a catalytic surface. The use of chemo-enzymatic systems on catalytic surfaces has proved to be suitable in solving biocompatibility and stability problems and correspondingly increasing the yield of esters formed. Therefore, finding an improved catalytic surface, and the sustainable optimal reaction conditions for enzymes will be vital to improving sugar ester conversion. This study highlights the different catalytic advances employed in the esterification of SEs.
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合成糖酯的催化方法
近年来,糖酯类表面活性剂因其生物相容性和广泛的工业应用而成为研究的热点。这一趋势为绿色合成化学的发展提供了新的方法和机遇。考虑到上述因素,在这项工作中提出了一项重要的审查,强调了催化合成具有最小危险副产物的SEs的效率。这些催化介质已被用于化学、生物和其他催化材料的各种影响。据报道,化学方法在制备和生物相容性方面显示出局限性。因此,为了解决这些缺点,采用了其他技术;离子液体(共晶溶剂),化学-酶系统和催化表面上的化学-酶系统。在催化表面上使用化学-酶系统已被证明适用于解决生物相容性和稳定性问题,并相应提高形成的酯的收率。因此,寻找一种改良的催化表面和可持续的最佳酶反应条件对提高糖酯转化率至关重要。本研究强调了不同的催化进展应用于酯化SEs。
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