Synthesized Tannin Foam from Tannin Resole Dehydrated by Hot Air Oven

IF 0.2 Q4 ENERGY & FUELS Journal of The Japan Institute of Energy Pub Date : 2021-10-20 DOI:10.3775/jie.100.225
Pattaraporn Suttaphakdee, Sutasinee Neramittagapong, S. Theerakulpisut, Arthit Neramittagapong, Tinnakorn Kumsaen
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Abstract

A simple method for synthesizing tannin foam (TF) from tannin resole (TR) was studied. Tannin was used as a substitute for phenol with a 10 wt% substitution ratio to form TR. The mixture of TR was dehydrated to get the TR with a solid content of 80% using a hot air oven. The dehydrated TR was used as an essential component for the formation of the TF. The functional groups, density, and compressive strength of the synthesized TF were tested by using an FTIR, ASTM D1622, and ASTM D1621, respectively. From the FTIR spectra, it was found that functional groups of TF were similar to phenol foam (PF). The addition of tannin increased the density and compressive strength of the TF. The density of tannin foam was 90.92 kg/m3, and the compressive strength of tannin foam was 0.25 MPa. Using tannin resole to make synthesized tannin foam proved to be a simpler method in dehydrating resole by hot air oven as compared with the conventional method. Moreover, the thermal performance of the TF was performed, and it was found that the TF showed a similar thermal performance to the PF.
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以单宁分解液为原料,用热风炉脱水合成单宁泡沫
研究了以单宁溶解(TR)为原料合成单宁泡沫(TF)的简单方法。以单宁代替苯酚,取代率为10 wt%,生成TR,再用热风炉对TR混合物进行脱水,得到固含量为80%的TR。脱水后的TR被用作TF形成的重要组成部分。采用FTIR、ASTM D1622和ASTM D1621分别对合成TF的官能团、密度和抗压强度进行测试。FTIR光谱分析发现,TF的官能团与苯酚泡沫(PF)相似。单宁的加入提高了TF的密度和抗压强度。单宁泡沫的密度为90.92 kg/m3,抗压强度为0.25 MPa。用单宁溶液制备合成单宁泡沫,与传统的热风炉脱水方法相比,是一种简单的方法。此外,对TF进行了热性能测试,发现TF与PF具有相似的热性能。
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