{"title":"Catalytic reactions at an artificial fractal interface: Simulation with the ‘Devil's Comb’","authors":"Pascal Mougin, Michel Pons, Jacques Villermaux","doi":"10.1016/S0923-0467(96)03104-1","DOIUrl":null,"url":null,"abstract":"<div><p>We have proposed the model of a 2-D fractal objects exhibiting an important contour length within a finite area. This structure offers a large internal interface can be used as a catalytic support. In the case of a single first-order reaction A → R at the interface, numerical simulations show evidence for a new diffusional regime due to the fractality of the support. In this regime, the rate of formation of product R no longer depends on the kinetic rate constant of the reaction.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"64 1","pages":"Pages 63-68"},"PeriodicalIF":0.0000,"publicationDate":"1996-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0923-0467(96)03104-1","citationCount":"7","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Chemical Engineering Journal and the Biochemical Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0923046796031041","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 7
Abstract
We have proposed the model of a 2-D fractal objects exhibiting an important contour length within a finite area. This structure offers a large internal interface can be used as a catalytic support. In the case of a single first-order reaction A → R at the interface, numerical simulations show evidence for a new diffusional regime due to the fractality of the support. In this regime, the rate of formation of product R no longer depends on the kinetic rate constant of the reaction.
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