Enhancement of the mechanical and acoustical properties of flexible polyurethane foam/waste seashell composites for industrial applications

IF 3.2 4区 工程技术 Q2 CHEMISTRY, APPLIED Journal of Cellular Plastics Pub Date : 2022-05-16 DOI:10.1177/0021955X221088392
AA Maamoun, AA El-Wakil, Tarek M. El-Basheer
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引用次数: 8

Abstract

The importance of this work is the use of waste seashells WSS (5, 10, 15, 20, 25, and 30 wt.%) as a bio-filler to enhance the mechanical and acoustical characteristics of flexible polyurethane foam (FPU). Petroleum-based polyol was partially replaced by 25% castor oil resulting in high renewable content. The WSS was characterized by X-ray photoelectron spectroscopy (XPS). The chemical structure and morphological features for castor oil-based flexible polyurethane waste seashells (CO-FPU-WSS) composites were detected using Fourier transform infrared (FTIR) and Scanning electron microscopy (SEM) techniques, respectively. Besides, the mechanical, non-acoustical and acoustical properties were investigated. The results indicated that bio-based FPU composites possessed better compressive strength than neat FPU foam. In addition, FPU composites enhance the sound absorption below 500 Hz. A 6 cm air gap behind the sample shifted the absorption toward 400 Hz (0.85) for CO-FPU-WSS 25% composite with a broader band. Thus, the FPU foam composite is considered a promising candidate for sound absorption applications such as for the automotive and building industries.
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增强工业用柔性聚氨酯泡沫/废贝壳复合材料的机械和声学性能
这项工作的重要性在于利用废贝壳WSS(5%、10%、15%、20%、25%和30% wt.%)作为生物填料来增强柔性聚氨酯泡沫(FPU)的机械和声学特性。部分以石油为基础的多元醇被25%的蓖麻油取代,从而产生高可再生含量。用x射线光电子能谱(XPS)对WSS进行了表征。采用傅里叶变换红外(FTIR)和扫描电镜(SEM)技术分别对蓖麻油基柔性聚氨酯废贝壳(CO-FPU-WSS)复合材料的化学结构和形态特征进行了检测。并对其力学性能、非声学性能和声学性能进行了研究。结果表明,生物基FPU复合材料的抗压强度优于纯泡沫FPU。此外,FPU复合材料增强了500hz以下的吸声性能。样品后面6 cm的气隙使CO-FPU-WSS 25%复合材料的吸收向400 Hz(0.85)方向移动。因此,FPU泡沫复合材料被认为是汽车和建筑工业等吸声应用的有前途的候选者。
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来源期刊
Journal of Cellular Plastics
Journal of Cellular Plastics 工程技术-高分子科学
CiteScore
5.00
自引率
16.00%
发文量
19
审稿时长
3 months
期刊介绍: The Journal of Cellular Plastics is a fully peer reviewed international journal that publishes original research and review articles covering the latest advances in foamed plastics technology.
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