J.Lawrence Hencher, Masood Khan, Farouq F. Said, Dennis G. Tuck
{"title":"Electrochemical preparation and structure of an unusual zinc(II) thiolato anionic cluster","authors":"J.Lawrence Hencher, Masood Khan, Farouq F. Said, Dennis G. Tuck","doi":"10.1016/0020-1650(81)80077-3","DOIUrl":null,"url":null,"abstract":"<div><p>The electrochemical oxidation of anodic zinc into a solution of PhSH + Et<sub>3</sub>N in CH<sub>3</sub>CN yields *Et<sub>3</sub>NH)<sub>2</sub>[Zn<sub>4</sub>(SPh)<sub>10</sub>]. The structure, as determined by X-ray crystallography, shows that the anion is a novel cluster based on a tetrahedral Zn<sub>4</sub>S<sub>10</sub> kernel.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80077-3","citationCount":"29","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800773","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 29
Abstract
The electrochemical oxidation of anodic zinc into a solution of PhSH + Et3N in CH3CN yields *Et3NH)2[Zn4(SPh)10]. The structure, as determined by X-ray crystallography, shows that the anion is a novel cluster based on a tetrahedral Zn4S10 kernel.
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