EVALUATING ETHYLENE PROPYLENE DIENE RUBBER FOR DYNAMIC APPLICATIONS INSTEAD OF NATURAL

B. Karaağaç, A. Bayram, Haluk Konyali
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引用次数: 1

Abstract

Natural Rubber (NR) has been used in dynamic applications for many years. NR has satisfactory resilience, vibration, and fatigue properties. Besides all these good properties, NR has quite poor aging resistance; also its service temperature is limited to about 90 °C. Improving aging characteristics of NR is a common problem for both rubber industry and academy. Nowadays, especially automotive industry has been focused on thermally resistant static and dynamic rubber based materials in new generation automobiles because of current strict emission regulations. There are a lot of attempts to improve service conditions of NR however; they are not comparable yet, with alternative saturated rubbers such as EPDM. In this study, a new grade EPDM, which had a high molecular weight, narrow molecular weight distribution, and tailor-made chain structure, has been studied in terms of rheological, mechanical, dynamic mechanical, aging, and low temperature properties for target dynamic applications. Especially possible service temperature and dynamic performance of EPDM were compared to that of NR based reference. It was concluded that, EPDM may be an assertive competitor to NR, if its chain structure is modified correctly.
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评价乙丙二烯橡胶替代天然橡胶的动态应用
天然橡胶(NR)已在动态应用中使用多年。NR具有令人满意的回弹、振动和疲劳性能。除了这些良好的性能外,NR的耐老化性很差;它的使用温度也限制在90°C左右。改善天然橡胶的老化特性是橡胶工业和学术界共同面临的问题。由于目前严格的排放法规,新一代汽车的抗热静态和动态橡胶基材料受到了汽车行业的关注。然而,有许多尝试改善NR的服务条件;他们还没有可比性,替代饱和橡胶,如EPDM。本研究从流变学、力学性能、动态力学性能、老化性能和低温性能等方面研究了一种具有高分子量、窄分子量分布和定制链结构的新型三元乙丙橡胶。并将EPDM的使用温度和动态性能与基于NR的参考材料进行了比较。结果表明,只要对三元乙丙橡胶的链结构进行适当的调整,三元乙丙橡胶将成为天然橡胶的有力竞争对手。
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