Relaxation of adsorption layers at solution/air interfaces using axisymmetric drop-shape analysis

R. Miller , R. Sedev , K.-H. Schano , C. Ng , A.W. Neumann
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引用次数: 67

Abstract

Axisymmetric drop-shape analysis is used to investigate the relaxation of surfactant adsorption layers after transient interfacial area changes, e.g. square-pulse or step-type disturbances. The response functions for sodium dodecyl sulfate solutions of different origin and for sodium tetradecyl sulfate are measured and interpreted in terms of a diffusion-controlled matter-exchange model. For both surfactant systems the data can be explained by considering small amounts of surface-active contaminations.

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利用轴对称液滴形状分析溶液/空气界面吸附层的松弛
采用轴对称液滴形状分析研究了表面活性剂吸附层在瞬态界面面积变化(如方波或阶跃扰动)后的弛豫。测量了不同来源的十二烷基硫酸钠溶液和十四烷基硫酸钠溶液的响应函数,并用扩散控制的物质交换模型解释了响应函数。对于这两种表面活性剂体系,数据可以通过考虑少量表面活性污染来解释。
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