Fabrication and Characterization of Dye Sensitized Solar Cells Based on TiO2

Ghufran M. Abbas, Aref S. Baron
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Abstract

Thin films of TiO2 nanostructures were prepared on FTO bases with different temperatures 140 ° C and 160 °C for 4 h. The XRD results showed that that there was an increase in the intensity of the peaks of the prepared (quadrangular) samples and a decrease in the FWHM was observed due to the increase in temperature as well as increase in the grain size in which the distance between the grains was decreased. According to the UV-Vis results, the energy band gap Eg was calculated from the reflectivity spectrum using the Kobelka - Monk equation. The increase in temperature has reduced the energy band gap, which shifting it towards the blue direction. FESEM, an increase in the surface thickness of the thin film due to an increase in the preparation temperature. The solar cell efficiency was decreased with increased in temperature. Where it was found the efficiency reduce rom 0.17% to 0.004% for As for 140 ° C and 160 ° C respectively
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二氧化钛染料敏化太阳能电池的制备与表征
在140℃和160℃的不同温度下,在FTO基底上制备TiO2纳米结构薄膜4 h。XRD结果表明,随着温度的升高,制备的样品(四边形)峰的强度增加,FWHM减小,晶粒尺寸增大,晶粒间距减小。根据UV-Vis结果,利用Kobelka - Monk方程从反射率谱计算了能带隙Eg。温度的升高减小了能带隙,使其向蓝色方向移动。在FESEM中,由于制备温度的升高,薄膜的表面厚度增加。太阳能电池的效率随着温度的升高而降低。在140°C和160°C时,效率分别从0.17%下降到0.004%
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