Improvement of energy properties of lignocellulosic waste by thermochemical conversion into biochar

Zorica R. Lopičić, Ana Antanasković, T. Šoštarić, Vladimir Adamović, M. Orlić, J. Milojković, M. Milivojevic
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Abstract

Peach stones, a valuable agro-industrial by-product available in many countries worldwide, comprise a renewable resource, which can be widely applied for multifunctional purposes. Its important advantages such as high-energy value, low ash content, low price and wide abundance, make peach stones an ideal fuel for energy production, but also for new materials synthesis. Although peach stones exhibit adequate combustion properties, allowing their direct use with minimal physical/chemical treatment, they often need further modification in order to improve their thermal properties, where slow pyrolysis is frequently used. This study aims to provide a practical and effective solution to the revalorization of waste biomass originating from the fruit processing industry, through slow pyrolysis in order to convert this waste into carbonaceous material - biochar. The thermo-chemical conversion of raw biomass resulted in a stable material with excellent fuel properties, with higher mass energy density and grinding ability, providing biochar with properties, in energy sense, similar or even better than a coal. Biochar has a higher fixed carbon content and a higher energy potential than biomass itself, and its application as a biofuel might reduce emissions of greenhouse gases, as it reduces the amount of waste landed and increases the share of energy generated from renewable sources.
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热化学转化为生物炭改善木质纤维素废弃物的能量特性
桃核是一种可再生资源,具有多种用途,是世界上许多国家的重要农工副产品。其高能值、低灰分、价格低廉、丰度广等重要优点,使桃核成为生产能源的理想燃料,也可用于新材料的合成。尽管桃核具有足够的燃烧性能,允许其直接使用,只需最少的物理/化学处理,但它们通常需要进一步改性以改善其热性能,其中经常使用缓慢热解。本研究旨在提供一种实用有效的解决方案,通过缓慢热解将来自水果加工业的废弃生物质再气化,将其转化为含碳物质-生物炭。原料生物质的热化学转化产生了一种稳定的材料,具有优异的燃料性能,具有更高的质量能量密度和研磨能力,使生物炭在能量意义上具有与煤相似甚至更好的性能。生物炭比生物质本身具有更高的固定碳含量和更高的能源潜力,并且它作为生物燃料的应用可能会减少温室气体的排放,因为它减少了废弃物的数量并增加了可再生能源产生的能源的份额。
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