Thanapon Sinkruason, Anupong Luangpangai, N. Charoenthai, A. Rittidech, P. Pulphol, N. Vittayakorn, T. Bongkarn
{"title":"Phase formation and electrical properties of SBNLT ceramics prepared via combustion technique","authors":"Thanapon Sinkruason, Anupong Luangpangai, N. Charoenthai, A. Rittidech, P. Pulphol, N. Vittayakorn, T. Bongkarn","doi":"10.1080/02670836.2023.2238415","DOIUrl":null,"url":null,"abstract":"This report investigates the effect of firing temperatures on the phase formation, microstructure, electrical, and energy storage properties of lead-free Sr0.3(Bi0.7Na0.67Li0.03)0.5TiO3 (SBNLT) ceramics, synthesised by combustion technique. The samples were calcined between 700°C and 900°C for 2 h and sintered between 1100°C and 1200°C for 2 h. The ceramics exhibited coexisting rhombohedral and tetragonal phases, which were confirmed by the Rietveld refinement technique. A morphotropic phase boundary (MPB) of the rhombohedral and tetragonal phases, with a ratio of 49:51, was obtained at the sintering temperature of 1175°C. The highest maximum dielectric constant (ε max = 4667), polarisation (P max = 28.80 µC/cm2) and energy density (W = 0.95 J/cm3), with a breakdown strength of 70 kV/cm, were achieved from the sample sintered at 1175°C.","PeriodicalId":18232,"journal":{"name":"Materials Science and Technology","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/02670836.2023.2238415","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This report investigates the effect of firing temperatures on the phase formation, microstructure, electrical, and energy storage properties of lead-free Sr0.3(Bi0.7Na0.67Li0.03)0.5TiO3 (SBNLT) ceramics, synthesised by combustion technique. The samples were calcined between 700°C and 900°C for 2 h and sintered between 1100°C and 1200°C for 2 h. The ceramics exhibited coexisting rhombohedral and tetragonal phases, which were confirmed by the Rietveld refinement technique. A morphotropic phase boundary (MPB) of the rhombohedral and tetragonal phases, with a ratio of 49:51, was obtained at the sintering temperature of 1175°C. The highest maximum dielectric constant (ε max = 4667), polarisation (P max = 28.80 µC/cm2) and energy density (W = 0.95 J/cm3), with a breakdown strength of 70 kV/cm, were achieved from the sample sintered at 1175°C.
期刊介绍:
《Materials Science and Technology》(MST) is an international forum for the publication of refereed contributions covering fundamental and technological aspects of materials science and engineering.