Theoretical Model for Spectroscopic Study of Cu+2, Co+2, and Fe+3 Dissolved in Ethanol with A Different Concentrations

I. Al-Sharuee
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Abstract

The absorption spectrum for three types of metal ions in different concentrations has been studying experimentally and theoretically. The examination model is by Gaius model in order to find the best fitting curve and the equation controlled with this behavior. The three metal ions are (Copper chloride Cu+2, Iron chloride Fe+3, and Cobalt chloride Co+2) with different concentrations (10-4, 10-5, 10-6, 10-7) gm/m3. The spectroscopic study included UV-visible and fluorescence spectrum for all different concentrations sample. The results refer to several peaks that appear from the absorption spectrum in the high concentration of all metal ions solution. The multiple absorption peaks continued even at the lowest concentration in the iron ion solution. Fluorescence spectrum shows intensive stimulating of the radiation strength was perceived in the manifestation of Cu+2, Co+2 and Fe+3. From modeling investigation, there are converge between experimental and theoretical results of the fluorescence spectrum for metal ions. Furthermore, identity and convergence which defined as (r2), are on average (0.995).
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不同浓度乙醇中Cu+2、Co+2和Fe+3的光谱研究理论模型
对三种不同浓度金属离子的吸收光谱进行了实验和理论研究。检验模型采用盖乌斯模型,以寻找最佳拟合曲线和受此行为控制的方程。三种金属离子分别为:氯化铜Cu+2、氯化铁Fe+3、氯化钴Co+2,浓度分别为10-4、10-5、10-6、10-7 gm/m3。光谱研究包括不同浓度样品的紫外可见光谱和荧光光谱。结果是指在高浓度全金属离子溶液中出现的几个吸收光谱峰。即使在最低浓度的铁离子溶液中,多重吸收峰仍然存在。荧光光谱显示,Cu+2、Co+2和Fe+3表现出强烈的辐射强度刺激。从模型研究来看,金属离子荧光光谱的实验结果与理论结果有一定的一致性。此外,恒等性和收敛性定义为(r2),平均为(0.995)。
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