Crystal Structure of Di-iso-butylammonium Thiolactatotriphenylstannate

Olaniran Atchade, Xueqing Song, R. Pike, G. Eng
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Abstract

The title compounds, [(iso-C4H9)2NH2][SnPh3(O2CCH(CH3)S)], crystallized in a monoclinic space group P21/n with the following cell parameters: a = 9.8537(2)A, b = 16.7775(3)A, c = 17.5845(3)A, β = 103.7740(10)°, V = 2823.48(9)A3, Z = 4 and Dx = 1.375 Mg m-3. The structure was refined to a final R value of 0.0222 for 5042 reflections [I > 2σ(I)]. The structure of the complex is ionic consisting of an anionic triphenyltin moiety and a cationic di-iso-butylammonium portion. In addition, a hydrogen bonding network between the cations and anions was observed.
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硫代乳酸三苯锡酸二异丁基铵的晶体结构
题目化合物[(iso-C4H9)2NH2][SnPh3(O2CCH(CH3)S)]在单斜空间群P21/n中结晶,晶胞参数为:a = 9.8537(2) a, b = 16.7775(3) a, c = 17.5845(3) a, β = 103.7740(10)°,V = 2823.48(9)A3, Z = 4, Dx = 1.375 Mg m-3。对于5042次反射,该结构的最终R值为0.0222 [I > 2σ(I)]。该配合物的结构为离子结构,由阴离子的三苯基锡部分和阳离子的二异丁基铵部分组成。此外,还观察到阳离子和阴离子之间的氢键网络。
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