Magnetically Retrievable Cobalt Ferrite Nanoparticles as Heterogeneous Catalyst for Synthesis of 1-Oxo-hexahydroxanthenes

M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake
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引用次数: 1

Abstract

In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.
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磁性可回收钴铁氧体纳米颗粒作为合成1-氧-六羟基蒽的非均相催化剂
本研究采用低成本化学沉淀法制备了磁性可分离的钴铁氧体纳米颗粒(CoFe2O4·NPs),并作为可重复使用的多相催化剂,用于在其他铁氧体中合成1-氧-六羟基蒽。通过x射线衍射和扫描电镜对纳米CoFe2O4的结构和形态进行了研究。目前的方案评估了各种水杨醛和1,3-二酮之间反应的熟练催化剂。该方案具有良好的反应条件、较短的反应时间、良好至优异的产物收率、易于纯化和催化剂可重复使用等优点,可达到5次催化循环而不显著损失催化活性,具有较好的实际应用前景。
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