M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake
{"title":"Magnetically Retrievable Cobalt Ferrite Nanoparticles as Heterogeneous Catalyst for Synthesis of 1-Oxo-hexahydroxanthenes","authors":"M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake","doi":"10.14233/AJOMC.2019.AJOMC-P207","DOIUrl":null,"url":null,"abstract":"In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.","PeriodicalId":8846,"journal":{"name":"Asian Journal of Organic & Medicinal Chemistry","volume":"198 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Organic & Medicinal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.14233/AJOMC.2019.AJOMC-P207","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.