Gas phase pulse radiolysis studies of excited states

Myran C. Sauer Jr.
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Abstract

The results and conclusions of the work of the author and co-workers on excited states proudced by pulse radiolysis of gaseous systems are summarized. Detailed consideration is given to systems containing naphthalene, for which the following subjects are discussed: (1) ionic and non-ionic mechanisms of excited state formation and their relative importance, (2) G-values of excited state formation and (3) energy partitioning in the non-ionic formation of excited states of naphthalene. Rate constants for reactions of excited states of naphthalene are summarized. The use of emission from excited states produced in ion-recombination reactions to determine rate constants for ion-recombination is also discussed.

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激发态的气相脉冲辐射分解研究
总结了作者和同事在气体系统脉冲辐射分解产生激发态方面的工作成果和结论。详细考虑了含萘的体系,讨论了以下问题:(1)激发态形成的离子和非离子机制及其相对重要性;(2)激发态形成的g值;(3)萘激发态非离子形成中的能量分配。总结了萘激发态反应的速率常数。本文还讨论了利用离子重组反应中产生的激发态发射来确定离子重组的速率常数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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