{"title":"FePO Catalysts for the Selective Oxidative Dehydrogenation of Isobutyric Acid into Methacrylic Acid","authors":"J. Millet","doi":"10.1080/01614949808007104","DOIUrl":null,"url":null,"abstract":"Abstract This review presents the iron phosphorus oxides used as catalysts for isobutyric acid oxidative dehydrogenation. Research on this catalytic system has been developed in the last decade and many publications have been devoted to this reaction, as it can be a step in a new process of production of methyl methacrylate. We emphasize particularly the nature of the active phase, the active centers, and the role of water and promoters. The mechanistic aspects of the reaction, which corresponds to an extension of the Mars and van Krevelen mechanism with a special role of water partial pressure, are discussed.","PeriodicalId":50986,"journal":{"name":"Catalysis Reviews-Science and Engineering","volume":null,"pages":null},"PeriodicalIF":9.3000,"publicationDate":"1998-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"56","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Reviews-Science and Engineering","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/01614949808007104","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 56
Abstract
Abstract This review presents the iron phosphorus oxides used as catalysts for isobutyric acid oxidative dehydrogenation. Research on this catalytic system has been developed in the last decade and many publications have been devoted to this reaction, as it can be a step in a new process of production of methyl methacrylate. We emphasize particularly the nature of the active phase, the active centers, and the role of water and promoters. The mechanistic aspects of the reaction, which corresponds to an extension of the Mars and van Krevelen mechanism with a special role of water partial pressure, are discussed.
期刊介绍：
Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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