Photodegradation of Rhodamine-B Dye under Natural Sunlight using CdO

D. Lavate, Vikas J. Sawant, A. Khomane
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引用次数: 2

Abstract

The present study includes synthesis of CdO thin film by simple and cost effective chemical bath deposition method. Cadmium monochloroaceatate were used for preparation of CdO thin film.  The structural, optical properties of CdO thin film were investigated with the help of X-ray diffraction (XRD) and UV-Vis NIR double beam spectrometry. The XRD studies revealed that annealed thin film shows crystalline in nature having 48.4 nm in size. The optical band gap of thin film was found to be 2.13 eV. Scanning Electron Microscopy (SEM) images shows sphere like structure which is closely arranged with each other. The presence of functional group was confirmed by Fourier Transform Infra Red (FTIR). Brunauer–Emmett–Teller (BET) surface area analysis confirm formation of a mesoporous CdO with 6.01 m2/g surface area and 31.96 nm average pore diameter. The photocatalytic activity of prepared thin film was checked by using Rhodamine-B as a model dye under natural sunlight and found to be 48%. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
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自然光照下用CdO光降解罗丹明- b染料
本研究包括用简单、经济的化学浴沉积法合成CdO薄膜。用一氯乙酸镉制备了CdO薄膜。利用x射线衍射(XRD)和紫外-可见-近红外双光束光谱法研究了CdO薄膜的结构和光学性质。XRD研究表明,退火后的薄膜为晶体,尺寸为48.4 nm。薄膜的光学带隙为2.13 eV。扫描电子显微镜(SEM)图像显示球体状结构,彼此紧密排列。傅里叶红外光谱(FTIR)证实了官能团的存在。比表面积分析证实,生成的中孔CdO比表面积为6.01 m2/g,平均孔径为31.96 nm。以罗丹明- b为模型染料,对制备的薄膜在自然光照下的光催化活性进行了检测,发现其光催化活性为48%。版权所有©2022作者所有,BCREC集团出版。这是一篇基于CC BY-SA许可(https://creativecommons.org/licenses/by-sa/4.0)的开放获取文章。
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